Section 20.1
Carbon is unusual : Bonds strongly to itself , Forms long chains or rings
Organic compounds – vast majority of carbon compounds
Exceptions – oxides and carbonates
Carbon Bonding: When carbon has 4 atoms bound to it these atoms have a tetrahedral shape.
Single bond – sharing one pair of electrons ( 2 electrons)
Double bond – sharing two pairs of electrons (4 electrons)
Triple bond – sharing three pairs of electrons (6 electrons)
Hydrocarbons – compounds composed of carbon and hydrogen
Saturated – all carbon-carbon bonds are single bonds
Unsaturated – containing carbon-carbon multiple bonds
Alkanes = all single bonds (General formula: CnH2n+2) Page 704
Normal = straight chair or unbranched hydrocarbon
Structural isomerism – occurs when 2 molecules have the same atoms but different bonds (page 705)
Naming Alkanes
The name for an alkane is based on Greek root with the suffix –ane.
meth = 1, eth=2, etc. See chart in book
Rules on page 710
Commas separate numbers.
Dashes separate numbers from letters.
Example 20.3 on page 706
Example and practice 20.4 (page 711)
and 20.5 (page 714)
Homework: Page 717, #1-4, (#4 name them too), 6, 8
Section 20.2
Halogen substitutions
-F fluoro
-Cl chloro
-Br bromo
-I iodo
One other common substitution to know
-NO2 (nitro)
alkenes – hydrocarbon containing carbon-carbon double bonds (General formula CnH2n )
alkynes – hydrocarbons containing carbon-carbon triple bonds (General formula CnH2n - 2 )
Rules for naming alkenes & alkynes on page 718
Example and Practice 20.6 on page 719
Single bonds rotate freely. Double and triple bonds are rigid…. no rotation.
Geometric isomers (same bonding – different shape)
Double bonds can be cis or trans
Aromatic hydrocarbons – cyclic unsaturated hydrocarbons with strong aromas
• Benzene – simplest aromatic hydrocarbon
Naming Aromatic Compounds (Page 722-724))
Monosubstituted benzenes: use the substituent name as a prefix of benzene
Disubstituted benzenes – use numbers to indicate the position of substituents and the substituent name as a prefix of benzene
Benzene as a substituent group = phenyl
C. Naming Aromatic Compounds
Example and practice 20.7 on page 725
Homework: Page 726, #1, 4-6
Section 20.3
A. Functional Groups (Page 727)
Functional group – additional atom or groups of atoms (containing elements in addition to H and C) found on a mostly hydrocarbon molecule
All alcohols contain the –OH group (hydroxyl).
Example and Practice 20.8 on page 729
Homework: Page 731, #1-4